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DIETHYL TERT-BUTYLMALONATE

Product Name
DIETHYL TERT-BUTYLMALONATE
CAS No.
759-24-0
Chemical Name
DIETHYL TERT-BUTYLMALONATE
Synonyms
AURORA KA-6574;Diethyl t-butylmalonate;DIETHYL TERT-BUTYLMALONATE;Diethyl 2-tert-butylmalonate;Diethyl tert-butylmalonate 96%;diethyl 2-tert-butylpropanedioate;diethyl (1,1-dimethylethyl)malonate;2-tert-Butylmalonic acid diethyl ester;N-(4-butylphenyl)-3-pyridinecarboxamide;1,1-dimethylethylpropandioc acid diethyl ester
CBNumber
CB4264123
Molecular Formula
C11H20O4
Formula Weight
216.27
MOL File
759-24-0.mol
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DIETHYL TERT-BUTYLMALONATE Property

Boiling point:
102-104 °C/11 mmHg (lit.)
Density 
1.014 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.425(lit.)
Flash point:
195 °F
pka
13.74±0.46(Predicted)
Water Solubility 
Immiscible with water.
BRN 
1781709
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Safety

Safety Statements 
23-24/25
WGK Germany 
3
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H227Combustible liquid

Precautionary statements

P403+P235Store in a well-ventilated place. Keep cool.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
278041
Product name
Diethyl tert-butylmalonate
Purity
96%
Packaging
5g
Price
$132.6
Updated
2024/03/01
Alfa Aesar
Product number
L09131
Product name
Diethyl tert-butylmalonate, 97%
Packaging
5g
Price
$126
Updated
2024/03/01
Alfa Aesar
Product number
L09131
Product name
Diethyl tert-butylmalonate, 97%
Packaging
1g
Price
$33.4
Updated
2021/12/16
Alfa Aesar
Product number
L09131
Product name
Diethyl tert-butylmalonate, 97%
Packaging
25g
Price
$431.65
Updated
2024/03/01
American Custom Chemicals Corporation
Product number
CHM0079562
Product name
DIETHYL TERT-BUTYLMALONATE
Purity
95.00%
Packaging
5G
Price
$909.08
Updated
2021/12/16
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DIETHYL TERT-BUTYLMALONATE Chemical Properties,Usage,Production

Uses

Diethyl tert-butylmalonate is used in the preparation of enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide.

Purification Methods

Dissolve it in Et2O, wash with aqueous NaHCO3, H2O, dry (MgSO4), filter, evaporate and distil the residue. Identify by hydrolysis to the acid and determine the neutralisation equivalent (theor: 80.0). The acid has m 155-157o effervescence [Hauser et al. J Am Chem Soc 64 2715 1942, Bush & Beauchamp J Am Chem Soc 75 2949 1953]. [Beilstein 2 IV 2027.]

DIETHYL TERT-BUTYLMALONATE Preparation Products And Raw materials

Raw materials

Preparation Products

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DIETHYL TERT-BUTYLMALONATE Suppliers

Austria 1 China 22 Germany 2 India 3 Switzerland 1 United Kingdom 4 United States 5 Global 38
Aladdin Scientific
Tel
+1-833-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57511
Advantage
58

759-24-0, DIETHYL TERT-BUTYLMALONATERelated Search:

2-Methylpropanedioic acid DIETHYL ISOPROPYLMALONATE Ethyl isovalerate Diethyl methylmalonate ETHYLMALONIC ACID ETHYL TERT-BUTYLACETATE METHYL TERT-BUTYLACETATE Dimethyl isopropylmalonate DIMETHYL TERT-BUTYLMALONATE Diethyl ethylmalonate 2-TERT-BUTYLPROPANE-1,3-DIOL (R)-(-)-3-HYDROXY-2-METHYLPROPIONIC ACID METHYL ESTER DIETHYL TERT-BUTYLMALONATE 3,3-DIMETHYL-1-BUTANOL (R)-2-Hydroxymethylbutanoic acid 3,3-Dimethylbutyric acid METHYL (S)-(+)-3-HYDROXY-2-METHYLPROPIONATE Dimethyl methylmalonate

  • AURORA KA-6574
  • DIETHYL TERT-BUTYLMALONATE
  • Diethyl 2-tert-butylmalonate
  • Diethyl t-butylmalonate
  • Propanedioic acid, (1,1-dimethylethyl)-, diethyl ester
  • diethyl (1,1-dimethylethyl)malonate
  • 1,1-dimethylethylpropandioc acid diethyl ester
  • (1,1-Dimethylethyl)propanedioic acid diethyl ester
  • 2-tert-Butylmalonic acid diethyl ester
  • Propanedioic acid, 2-(1,1-diMethylethyl)-, 1,3-diethyl ester
  • Diethyl tert-butylmalonate 96%
  • N-(4-butylphenyl)-3-pyridinecarboxamide
  • diethyl 2-tert-butylpropanedioate
  • 759-24-0
  • CH33CCHCOOC2H52
  • Building Blocks
  • Carbonyl Compounds
  • C10 to C11
  • Organic Building Blocks
  • Esters
  • C10 to C11
  • Carbonyl Compounds
  • Esters